Mironova Labs

TMHD Precursors for Battery & Energy Applications

Halide-free cathode coatings for cycling stability

For battery researchers and engineers developing conformal ALD coatings for cathode protection and solid electrolytes

Supported by peer-reviewed research≥99% purityHalide-freeUS-manufacturedPowder-coating compatible

Your Challenge. Our Answer.

We understand the specific problems you face — and we built solutions for each one.

The Problem

Halide-containing precursors deposit Cl/F contaminants that corrode battery electrodes and degrade cycling performance

Mironova’s Answer

TMHD precursors are entirely halide-free — no Cl or F contamination pathway. Safe for electrode surface chemistry.

The Problem

Precursor thermal decomposition in fluidized-bed or rotary reactors causes non-uniform coatings on powder substrates

Mironova’s Answer

TMHD’s exceptional thermal stability enables predictable dosing even in demanding powder-coating reactor environments

Published Evidence

Key findings from peer-reviewed literature relevant to your application.

ALD for Battery Cathodes

ALD coatings on cathode powders (NMC, LFP) improve cycling stability by preventing surface degradation. Ultra-high precursor purity is critical for electrochemical stability.

Meng et al., Adv. Mater. 2012

Halide-Free Precursor Advantage

Residual halides from precursors (e.g. HfCl₄) act as charge traps and contamination sources in thin films. Halide-free TMHD precursors eliminate this risk at the molecular level.

Park et al., J. Phys. Chem. C 2016; Meng et al., Adv. Mater. 2012

Battery ALD Guidelines

  • Coating thickness: 0.5–5 nm (submonolayer to few nm)
  • Application: fluidized-bed ALD or rotary reactor
  • Electronic-grade purity required for long-term cycling
  • Ozone (O₃) required as oxidant for all TMHD precursors

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Receive halide-free precursor samples with analytical data for battery coating process development.

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Related Resources

Technical data, product specifications, and application guidance.