Mironova Labs

TMHD Precursors for Battery & Energy Applications

Halide-free cathode coatings for cycling stability

For battery researchers and engineers developing conformal ALD coatings for cathode protection and solid electrolytes

≥99%

Assay Purity

Halide-Free

No Corrosion Path

ALD

Conformal Interfaces

US-Made

Domestic Supply

Supported by peer-reviewed research≥99% purityHalide-freeUS-manufacturedPowder-coating compatible

ALD-deposited oxide coatings on cathode powders and electrode interfaces can improve battery cycling stability and lifetime. Mironova’s halide-free TMHD precursors deposit conformal coatings without introducing corrosive chlorine or fluorine species that degrade electrolyte interfaces.

Challenges & Solutions

Your Challenge. Our Answer.

We understand the specific problems you face — and we built solutions for each one.

The Problem

Halide-containing precursors deposit Cl/F contaminants that corrode battery electrodes and degrade cycling performance

Mironova’s Answer

TMHD precursors are entirely halide-free — no Cl or F contamination pathway. Avoids corrosive byproducts at electrode interfaces.

The Problem

Precursor thermal decomposition in fluidized-bed or rotary reactors causes non-uniform coatings on powder substrates

Mironova’s Answer

TMHD’s exceptional thermal stability enables predictable dosing even in demanding powder-coating reactor environments

Published Research

Published Evidence

Key findings from peer-reviewed literature relevant to your application.

ALD for Battery Cathodes

ALD coatings on cathode powders (NMC, LFP) improve cycling stability by preventing surface degradation. Ultra-high precursor purity is critical for electrochemical stability.

Meng et al., Adv. Mater. 2012

Halide-Free Precursor Advantage

Residual halides from precursors (e.g. HfCl₄) act as charge traps and contamination sources in thin films. Halide-free TMHD precursors eliminate this risk at the molecular level.

Park et al., J. Phys. Chem. C 2016; Meng et al., Adv. Mater. 2012

Application Notes

Battery ALD Guidelines

Coating thickness: 0.5–5 nm (submonolayer to few nm).
Application: fluidized-bed ALD or rotary reactor.
Electronic-grade purity required for long-term cycling.
Ozone (O₃) required as oxidant for all TMHD precursors.
For full ALD windows, vapor pressure curves, and peer-reviewed studies, please visit our Metal-Organic Precursors Science Hub.

Why Mironova

Your Advantage with Mironova

01

Halide-Free Interphase Control

TMHD precursors deposit oxide coatings without introducing Cl or F that can corrode electrode materials or degrade electrolyte interfaces in battery architectures.

02

Conformal 3D Coverage

ALD provides uniform coatings on high-aspect-ratio battery electrode structures where conventional methods cannot reach. Critical for solid-state and 3D battery designs.

03

Reproducible Nanoscale Coatings

Sub-nanometer thickness control enables systematic study and optimization of artificial SEI layers, cathode coatings, and interfacial barriers.

04

Multi-Metal Platform

ZrO₂ and other oxide coatings from the TMHD precursor platform. Contact us to discuss Al₂O₃ and additional metal-oxide options for your coating requirements.

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Get product specifications, CoA samples, and pricing for your evaluation.

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FAQ

Frequently Asked Questions

Common technical questions about this product line, answered by our scientific team.

ALD-deposited oxide coatings (e.g., ZrO₂, Al₂O₃) on cathode powders have been linked to improved cycling stability in published studies. The conformal coating acts as an artificial interphase that controls surface degradation. Contact us to discuss which precursor fits your application.
Currently, ALD coatings for batteries are primarily used in R&D and pilot-scale development. The same precursor quality and process reproducibility that matters at research scale will be critical as these architectures move toward production.
Our TMHD platform supports Al, Zr, and other metals relevant to battery interphase engineering. Contact us to discuss your specific coating requirements and target oxide compositions.

Request Evaluation Samples

Receive halide-free precursor samples with analytical data for battery coating process development.

Or call us at +1 (973) 244-0393

Related Resources

Technical data, product specifications, and application guidance.